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美國布魯克海文儀器公司>技術文章>Nanobrook Omni測量應用案例-48

技術文章

Nanobrook Omni測量應用案例-48

閱讀:323          發布時間:2018-10-10
 文獻名:Degradation of atrazine by ZnxCu1xFe2O4 nanomaterial-catalyzed sulfite under UVvis light irradiation: Green strategy to generate SO4 

 

作者:Ying Huanga, Changseok Hana, Yiqing Liua, Mallikarjuna N.Nadagoudab, Libor Machalac, Kevin E.OShead, Virender K.Sharmae, Dionysios D.Dionysioua 

a    Environmental Engineering and Science Program, University of Cincinnati, Cincinnati, OH 45221, USA

b    Center for Nanoscale Multifunctional Materials, Mechanical & Material Engineering, Wright State University, Dayton, OH 45431, USA

c    Regional Centre of Advanced Technologies and Materials, Department of Experimental Physics, Faculty of Science, Palacký University, 771 46 Olomouc, Czech Republic

d    Department of Chemistry and Biochemistry, Florida International University, Miami, FL 33199, USA

e    Program for the Environmental and Sustainability, Department of Environment and Occupational Health, School of Public Health, Texas A&M University, College Station, TX 77843, USA

 

摘要:Degradation of atrazine, a widely-used herbicide, by a novel advanced oxidation process was investigated through photo-catalyzing sulfite, the precursor of sulfate radical (SO4) in this study, by zinc-copper ferrites (ZnxCu1xFe2O4) under UVvis light irradiation. The ZnxCu1xFe2O4 with different ratios of Zn to Cu was synthesized through a facile sol-gel combustion method, and characterized by X-ray powder diffractometry, scanning electron microscopy, transmission electron microscopy, porosimetry, and UVvis diffuse reflectance spectroscopy, and by a vibrating sample magnetometer and Mössbauer spectrometer. The Zn0.8Cu0.2Fe2O4 demonstrated the highest photocatalytic ability to activate sulfite for the degradation of atrazine under current experimental conditions. The sulfate radical generated in the UVvis light/Zn0.8Cu0.2Fe2O4/sulfite system was identified as the main reactive species through radical quenching experiments and measuring two important byproducts (atrazine-desethyl and atrazine-desisopropyl). The XPS spectra of fresh and used catalysts were analyzed to further elucidate the reaction mechanisms. There are two possible approaches to produce SO4: the oxidation of sulfite by photo-generated holes and the accelerated decomposition of metal-sulfito complexes (Fe(III)-sulfito and Cu(II)-sulfito) on the surface of Zn0.8Cu0.2Fe2O4. Based on the detected byproducts, the transformation pathways of atrazine by UVvis light/Zn0.8Cu0.2Fe2O4/sulfite were proposed as well. After the complete decomposition of atrazine, the used catalysts could be magnetically recovered using a magnet and no sulfite remained in the system. The results suggest that the UVvis light/Zn0.8Cu0.2Fe2O4/sulfite system is a greenadvanced oxidation technology for future application in wastewater treatment.

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