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技術文章

pH-Induced fragmentation of colloids based on responsive self-assembled copper(II) metallopolymers

閱讀:287          發布時間:2018-11-10
 作者:Bin Wang,a  Margot Jacquet,b  Kunzhou Wang,a  Kun Xiong,a  Minhao Yan,a  Jérémie Courtois*a  and  Guy Royal*ab  

a State Key Laboratory C*tion Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, China

b Université Grenoble Alpes, CNRS, Département de Chimie Moléculaire (UMR 5250), F38400 Grenoble, France

 

摘要:Colloidal particles based on self-assembled Cu2+ coordination polymers were fabricated following a one-step process. These particles were shown to be stimuli-responsive. In particular they can be readily disassembled in acidic conditions. This effect originates from a pH-induced fragmentation of the polymer chains into dinuclear Cu2+ complexes.

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